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I would get a straight 24 and one of Supermans 100A surepowers... There was quite a discussion on the quality of the double-alt not all that long ago.
In the end pulling 12V out of the middle of a 24V string and trying to charge 12 and 24 simultaneously is a problem prone way of doing a dual...
It should work, but you need a converter with a very low cutout voltage so it doesn't drop off line when you crank the engine.
They make these for commercial vehicles to provide a standalone 12V or to float the 12V center of a 24V battery string like the 24/12 alternator does.
Was working...