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The key is to assume no coating can be 100% defect free. Zinc based coatings are the only ones that can protect a defect. You best system would be an inorganic zinc coating with calcium sulfonate wax topcoat.
GM has been using gelled calcium sulfonate as an undercoating lately. It's self-healing and can be applied to marginally prepared surfaces.
https://www.daubertchemical.com/store/product-list/corrosion-prevention/nox-rust-x-121b
It's wax-like so you don't want to use it in places it might rub...
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