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They're mostly still available. These aren't solvent based or have flash points over 140F so they aren't controlled under the VOC rules.
The Big Orange is orange based and cost is highly dependent on winter temps. The price goes up if there is a winter freeze.
I have noticed a lack of caustic...
Caustic degreasers work great but I have noticed that they remove frame paint that has had oil/grease sitting on it for a long time. Zep Big Orange is a powerful degreaser that I have found to be safe for paint. Simple Green etches paint. A solvent gun can be useful.