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IF you need a 3rd battery, use an alternator for charging, TM_america sells a good mount.the most important question is (after the total load) how much capacity do you need. It makes no sense to install an alternator for a cellphone charger.
If you want to run a cooler or little fridge or something else without the engine all the time running, you want the saftey and capacity of a 3rd battery.
Every fire truck or emergency vehicle that i know has a independant battery for the electrical consumers to keep the starter battery full.