On new engines, the exhaust valves tend to get stuck from no-use, because of the very tight lip seal not allowing any oil to keep the guide and shaft wet, to avoid rust build-up.
First cranking then bends the pushrod which usually dislocates it from the rocker.
Turn the crank until that piston is way up, disassemble retainer and spring; remove that oil seal; use plenty of PB-blaster around the stem; reassemble the spring & retainer and then tap on the valve until it moves freely again.
Never attempt to straighten- and re-use a bent pushrod; replace it!