If it is totally stock, only your starter is 24 volt.
Everything else runs on 12 volts.
Do the Doghead starter relay conversion.
The stock starter relay is poor quality and has a history of sticking which can burn up your starter.
Go through the glow plug system.
There is a relay upgrade for that as well as a better glow plug control card available.
Fuel pumps are a known weakness. The fuel pump is on the passenger side of the block and it just pumps fuel at low pressure up to the injection pump.
Might be a good idea to replace it due to age alone.
The 10 bolt rear gov lock axle has a few weaknesses.
The axle bearings ride directly on the axle shafts. Don't assume because of low mileage that there is not a great deal of wear there.
Jack up the rear end and see if there is play.
Put a finger along the gap between the brake drum and backer plate while an assistant lifts on the wheel.
The rear stud shock mounts have a habit of becoming loose.
Grab the top of the shock and twist to see it it is loose.
All Chevy Blazers prior to 1987 tend to develop frame cracks under or near the steering box.
Have someone turn the steering wheel while you observe the frame under the steering box.
If there are cracks, you'll see them.
There are kits( to repair them and a brace (Off road Design) to reinforce the area if you plan on tires 33" or larger.
Headlight wiring connections are notorious for becoming corroded resulting inone or more dim lights.
On a truck this old all grounds; frame to battery, frame to frame, everywhere you find them, should be removed and cleaned.
Brake calipers can become sticky with age.
Easily replaced, same as civilian version.
The rear gov lock is not known for strength with larger than stock tires or when used off road.
The stock 3.08 ratio gearing is very tall and will cause the turbo 400 transmission to slip if you try and tow heavy things at high speeds uphill.
The NP 208 transfer case is excellent as long as you keep the fluid fresh.
It takes Automatic Transmission Fluid NOT GEAR OIL.
The ac compressor would need to be swapped from a civilian 6.2 equipped truck or blazer but since you have an extra alternator already occupying that spot, it would take some doing.
You would need the interior evap core, the radiator mounted condenser, all the hoses, the receiver dryer, the compressor and all the brackets.
I don't know man.
I think I would just crack a window instead.