Rotating makes no difference at all. Consider the circuit diagram symbol for a battery (below).
Note that all the cells (nominal 2.0 volts) are in a string together. Our pictured example is a 10 Volt battery if we assume those are lead-acid cells.
Because they're in a string together, if a current passes through one cell, the same amount of current passes through all the cells. There's no difference between the first and last cells in a string as far as current availability is concerned.
Chances are good that the cells do not charge and discharge identically. When charging, it is important to charge the battery until the most discharged cell is fully charged. The 'right' way to do this is to measure the specific gravity of each cell with a hydrometer during charging, and when the lowest cell reports a 'fully charged' specific gravity, you're done. It's a pain, and almost nobody does it.
The good news is that flooded lead-acid cells tolerate a mild overcharge very well. So SOP for decades has been to 'float' the battery slightly above the full charge voltage, and accept that a little electrolyte will be hydrolyzed ('boiled off') from the fully charged cells while the lowest cell is brought up to full charge. As long as you ramp the current down to something below about c/20, this method works well.
All constant voltage charging circuits work on this principle - full charge static voltage on a 12 cell string should be about 25.5 volts. Applying an extra 1-2 volts across the string still only amounts to a difference of 0.15 volts/cell, which means a very small amount of current. This is what is meant by the term 'float charging' - the string 'floats' at some voltage above its full charge voltage all the time. This works great in vehicles, which tend to be shut off for a minimum of 8-12 hours at a time.
The downside is that the string is always hydrolyzing a little electrolyte whenever the battery is fully charged and the charging system is working, which (along with high underhood temperatures) results in the requirement for a periodic topping-up of the cells with deionized water to replenish lost electrolyte. This is also one reason why batteries in 100% duty cycle installations tend to have much more elaborate charge control programs than the simple constant voltage system used on vehicles. 'Battery Tender' type chargers also have more elaborate charge programming, which is one reason that they can make even a puny motorcycle battery last forever.
So skip rotating the batteries in the string and, if you're feeling like you have to do something, pop the caps and check the fluid level and specific gravity of the cells.