duvac...
I had the same troubles you describe.since it's a converted ambulance,you should see a small black/aluminum box mounted just aft of the duvac.this little box is the switch (don't ask me just how it works...i just know what it does) that cycles one of the alternators to either charge the front batt' or stay off under light loads.turns out,mine was fried,and causing a grounding problem and a battery drain.
That switch set-up is what's supposed to keep the batteries charge balanced,as the original setup is a "center tapped" battery bank.the system as original,never seemed to work very well at all.as you mention,it usually fries the rear battery due to over charge,and kills the front due to undercharge/sulfation.the system as original,was "overthought" and under engineered,but to be fair,i don't think that there were a lot of really high capacity 24-v alternators available off the rack at that time that would suit.
in my case,not really aware of the precise cause of my problems,i pulled one alternator and the entire duvac system.i then installed a bettery equalizer,which serves to provide a center tap in the battery bank,and allows for precise control of charging.i wanted to keep 24/12-volt as i still had the 24-v air conditioning and rear heater installed.this has worked perfectly and has proven very reliable,in a wide range of temperatures and conditions.
Since you have an already converted truck body,i don't imagine you have a real need for 24-volt.a 12-volt conversion would work well for you.iirc-rosscommon equipment still has instructions on-line to do the conversion.if you need 24-v,then you might pull an alternator and rewire the system to use your original duvac (blue box) as an equalizer,as it IS an equalizer.one alternator only though,and this assumes it's in good order.pull the diode switch thingy and all attendant wiring and toss it.if the blue box is bad,and you still want 24-v...then a new equalizer is in order.you should be able to get one with sufficiant capacity on the 12-volt side (about 60 amps) for around $ 400-U.S.
if your concerned about power...the leece-nevilles are big.one at 24-volt will provide plenty of power,as they have a nominal 100 amp output.that output at 24-v is plenty of juice.