Jump start a 24 Volt vehicle with 12 Volt only works, if at least one of the two batteries is in usable condition! That's what the diagrams of the other guys show. Remember: If the engine is not perfect on compression and the injection pump and the injectors do not work very perfect, you WILL fail. The 6.2 l Diesel needs a minimum of 200 rpm to start! Never use starting fluids, it will crack the bearings and , if very unlucky, bend the piston rods. I have over 17 years of experience!
Normally two choises: Buy new batteries (2 of them, 100 AH NATO block is not required, a 85 AH standard batterie is fine (Newly available as 95 AH thanks to BMW X5 and simelar vehicles (SUV)) or take them out and properly try to recharge them, if they are still any good.
Normally warenty on batteries is 2 to a maximum of 5 years. If they are older, discard them, buy new ones! Try to get HD (in Germany called RF: rüttelfest) Batteries which are used in trucks (real big ones) or working mashines, they last normally 2 to 5 years longer for only a little more money.
By the way: batteries MUST be recharged at least after 6 month, better every 6 to 8 weeks due to natural discharge of 1,5 % to 2 % every day.
Wolf