If your spray gun does not have a regulator on the handle you will need a good regulator to control the pressure at the gun. I use a mini regulator on my HVLP and run high pressure to the gun.
You will have to prime the surfaces and that is a great chance to gain the experience in proper mixing and patterns of coverage. Your spray gun should always remain at the same relative angle to your work piece. This keeps the pattern of application from the nozzle the same. When you apply any paint, from gloss, to semi to flat paint, you look for the flood, or wet to follow your spray gun to ensure you are getting a seal on the surface. The application process is a dance between getting just enough to seal and protect the surface and too much which will result in a droop or sag or worse yet a run in the paint.
After the first pass, use half lap of spray pattern on each successive pass to be sure you do not miss a spot. Alternating horizontal passes and vertical passes in seaparate coats guarantees you get even protection and coverage.
In thinning paint, follow the manufacturer's instructions and be very aware of the temperatures because in my experience it is often times colder in the area where you are spraying that it is in the mixing area. It helps to use a paint strainer to ensure you do not have large particles in your paint, but some paints do not lend themselves to these filters due to their thick consistency.
Be sure to have good ventilation, and wear a proper mask to protect you from the fumes and particles in the paint that are airborne and are a threat to you and yours when you are painting.
An explosion proof exhaust fan is used in a spray booth. I generally spray outdoors these days especially on large items like a deuce so your venitilation problems are solved there.
If it is dusty where the truck, or other item is located you are painting, wet the ground, or floor to keep the dust from contaminating your workpiece.
Lastly, I would do a practce piece and get a feel for the process on that before taking on the big things....
Hope this helps
RL