Yeah. Uhh, I don't know where you got the 14v from I have always been talking about a 24v system.
The GM 1-wire 65 amp 12v (14v output) self-energizing alternator is, by a
HUGE margin, the most often used alternator when going away from OEM.
You said one-wire, I made the reasonable assumption that you meant that unit.
If there's a 24v 60 amp internally regulated single wire unit out there, I'm unaware of it, and so is google. The 40 amp units have barely higher output than the 12v GM alternator.
Also, you mentioned wanting to use Optima Batteries. I suggest not. They don't have the amp output or the reserve of the big square commercial batteries, nor do they last as long (3-4 years is typically it). They're great for applications in which a battery will get jarred (drag racing, rock crawling, etc), which can cause the plates to short in a normal lead-acid battery. But they do not perform as well under everyday use. If they did, I'd be running them. Instead, I pay just as much for a top quality conventional battery in the form of Interstate green tops.
The longer one is in the business of fixing vehicles, the more one realizes that A) the engineers/designers know more about this stuff than we do , B) increased performance comes at the cost of reliability and C) alot of aftermarket parts do not work as well as advertised. Thoughtful consideration before modifying and careful matching of components are virtues of those of us who've been there and done that. The ones who benefit most are the people who listen to the veterans who wasted alot of time and money learning the hard way.