A bona fide chemical lab that charges large dollars did some work for me on the subject of DOT 3 and DOT 5 a few years ago. I incorporated some of this into an article for MVM a few years ago.
I'll hit some high points for you. DOT5 is purple, DOT3 is nearly clear. If you mix them the purple dye in the DOT5 ABSOLUTELY WILL EVERY TIME leave the DOT5 and move to the DOT3. The DOT3 becomes purple, and the DOT5 clear. If you look at a sample of the two in container it will look from the color to be evenly divided - but the colors WILL be backwards. So, do NOT rely on color if you think both fluids are in your system.
The army conducted two very major, extensive (couple of years) and expensive tests on silicone brake fluid. Results of both tests were that there was no degradation of the fluid or brake system components caused by mixing the fluid. The sole problem with this is that mixing the two negates the antihygroscopic (non-water absorbing) nature of the DOT5. Hence the army issued emphatic orders that when converting the system should be completely purged.
Lab tests I had done a couple years ago resulted in the same conclusion. HOWEVER, many folks on this board like CCATLETT state that there are problems with this - therefore this winter I'll begin a controlled test over some time and report the findings I get.
You be the judge on the "goo" issue - but I can tell you with 100% certainity if you even think the two fluids have been mixed, don't trust the color. Take a small sample of the brake fluid and add a few drops of water - if they mix, its DOT3, if it doesn't, its DOT5.
Hope this helps,
David Doyle